Email this article Effect of Association on Nucleophilic Addition of (Meth)acrylic Aminoamides to Acrylic Acids in Aqueous Solutions
- Authors: Kazantsev О.А.1, Baruta D.S.1, Kamorin D.М.1, Shirshin K.K.1,2, Sivokhin А.P.1
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Affiliations:
- R.E. Alekseev Nizhny Novgorod State Technical University
- N.I. Lobachevsky State University of Nizhny Novgorod
- Issue: Vol 88, No 4 (2018)
- Pages: 641-645
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222120
- DOI: https://doi.org/10.1134/S1070363218040059
- ID: 222120
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Abstract
Reactions of nucleophilic addition of N-(3-dimethylaminoalkyl)(meth)acrylamides to acrylic, N-acryloylaminoacetic, and 2-acrylamido-2-methylpropanesulfonic acid with the formation of betaines revealed an unusual dependence of the initial rate and equilibrium conversion on concentration of the reagents. The observed effects were explained by structural features of the reagents and the products.
About the authors
О. А. Kazantsev
R.E. Alekseev Nizhny Novgorod State Technical University
Email: kkshirshin@mail.ru
Russian Federation, ul. Minina 24, Nizhny Novgorod, 603950
D. S. Baruta
R.E. Alekseev Nizhny Novgorod State Technical University
Email: kkshirshin@mail.ru
Russian Federation, ul. Minina 24, Nizhny Novgorod, 603950
D. М. Kamorin
R.E. Alekseev Nizhny Novgorod State Technical University
Email: kkshirshin@mail.ru
Russian Federation, ul. Minina 24, Nizhny Novgorod, 603950
K. K. Shirshin
R.E. Alekseev Nizhny Novgorod State Technical University; N.I. Lobachevsky State University of Nizhny Novgorod
Author for correspondence.
Email: kkshirshin@mail.ru
Russian Federation, ul. Minina 24, Nizhny Novgorod, 603950; Nizhny Novgorod
А. P. Sivokhin
R.E. Alekseev Nizhny Novgorod State Technical University
Email: kkshirshin@mail.ru
Russian Federation, ul. Minina 24, Nizhny Novgorod, 603950
