Email this article Hydrogenation of Ketones on Dispersed Chiral-Modified Palladium Nanoparticles
- Authors: Nindakova L.O.1, Strakhov V.O.1, Kolesnikov S.S.1
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Affiliations:
- Irkutsk National Research Technical University
- Issue: Vol 88, No 2 (2018)
- Pages: 199-207
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/221984
- DOI: https://doi.org/10.1134/S1070363218020044
- ID: 221984
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Abstract
Hydrogenation of acetophenone and esters of ketoacids with molecular hydrogen in the presence of the Pd(acac)2–(–)-cinchonidine–H2 catalytic system has been studied. The dependence of the molar ratio of (–)-cinchonidine/Pd on size and shape of palladium nanoparticles, formed in the system, also on reaction rate and enantioselectivity has been established. The nature of the regularities observed for the Pd(acac)2–(–)-cinchonidine–H2 catalytic system was discussed.
About the authors
L. O. Nindakova
Irkutsk National Research Technical University
Author for correspondence.
Email: nindakova@istu.edu
Russian Federation, ul. Lermontova 83, Irkutsk, 664074
V. O. Strakhov
Irkutsk National Research Technical University
Email: nindakova@istu.edu
Russian Federation, ul. Lermontova 83, Irkutsk, 664074
S. S. Kolesnikov
Irkutsk National Research Technical University
Email: nindakova@istu.edu
Russian Federation, ul. Lermontova 83, Irkutsk, 664074
