Ferrocene Macrocyclic Schiff Base Complex: Synthesis, Structure and Recognition Properties for Dual Hg2+ and Cu2+
- Authors: Liu X.1, Xiang Y.1, Ma X.1, Ren G.1, Gao L.1
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Affiliations:
- Key Laboratory of Synthetic and Natural Chemistry of the Ministry of Education, Chemical Engineering Institute
- Issue: Vol 87, No 12 (2017)
- Pages: 2986-2988
- Section: Letters to the Editor
- URL: https://journals.rcsi.science/1070-3632/article/view/221801
- DOI: https://doi.org/10.1134/S1070363217120428
- ID: 221801
Cite item
Abstract
A probe based on ferrocene structure has been designed, synthesized and elucidated from the single crystal X-ray method. It demonstrated fluorescence response to Hg2+ and Cu2+ in CH3OH. The results indicated that the title complex could be applied in the multianalyte detection. Binding ability of receptor 3 in CH3OH was tested for various cations (Fe3+, Co2+, Cu2+, Zn2+, Cd2+, Hg2+, Pb2+, and Ba2+ in water). The computed binding constants for Hg2+ and Cu2+ indicated a distinct absorbance shift. The receptor is an attractive array due to its distinct absorbance shift profile in a semi-aqueous phase, making it applicable in biology, environmental sciences and material chemistry.
About the authors
Xiaoju Liu
Key Laboratory of Synthetic and Natural Chemistry of the Ministry of Education, Chemical Engineering Institute
Author for correspondence.
Email: liuxiaoju0628@163.com
China, Chongwen av. 4, Yulin, Shaanxi Province, 719000
Yulin Xiang
Key Laboratory of Synthetic and Natural Chemistry of the Ministry of Education, Chemical Engineering Institute
Email: liuxiaoju0628@163.com
China, Chongwen av. 4, Yulin, Shaanxi Province, 719000
Xiangrong Ma
Key Laboratory of Synthetic and Natural Chemistry of the Ministry of Education, Chemical Engineering Institute
Email: liuxiaoju0628@163.com
China, Chongwen av. 4, Yulin, Shaanxi Province, 719000
Guoyu Ren
Key Laboratory of Synthetic and Natural Chemistry of the Ministry of Education, Chemical Engineering Institute
Email: liuxiaoju0628@163.com
China, Chongwen av. 4, Yulin, Shaanxi Province, 719000
Liguo Gao
Key Laboratory of Synthetic and Natural Chemistry of the Ministry of Education, Chemical Engineering Institute
Email: liuxiaoju0628@163.com
China, Chongwen av. 4, Yulin, Shaanxi Province, 719000