Synthesis of Binuclear Antimony Complexes with Tetraketonate Ligands


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Abstract

Reactions of tetraphenylantimony bromide with sodium salts of 3,8-dioxodeca-4,6-diene-5,6-diol and 2,2,9,9-tetramethyl-3,8-dioxodeca-4,6-diene-5,6-diol at various molar ratios of the reactants have been studied. Irrespective of the molar ratio, binuclear chelate complexes Ph4Sb[OC(R)CHC(O)(O)CCH(R)CO]SbPh4 are formed. The structures of the resulting complexes were established by the methods of IR and NMR spectroscopy.

About the authors

E. V. Artem’eva

National Research South Ural State University

Author for correspondence.
Email: katriona-art@yandex.ru
Russian Federation, pr. Lenina 76, Chelyabinsk, 454080

O. K. Sharutina

National Research South Ural State University

Email: katriona-art@yandex.ru
Russian Federation, pr. Lenina 76, Chelyabinsk, 454080

V. V. Sharutin

National Research South Ural State University

Email: katriona-art@yandex.ru
Russian Federation, pr. Lenina 76, Chelyabinsk, 454080


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