Synthesis of Binuclear Antimony Complexes with Tetraketonate Ligands
- Authors: Artem’eva E.V.1, Sharutina O.K.1, Sharutin V.V.1
-
Affiliations:
- National Research South Ural State University
- Issue: Vol 87, No 12 (2017)
- Pages: 2904-2905
- Section: Letters to the Editor
- URL: https://journals.rcsi.science/1070-3632/article/view/221738
- DOI: https://doi.org/10.1134/S1070363217120283
- ID: 221738
Cite item
Abstract
Reactions of tetraphenylantimony bromide with sodium salts of 3,8-dioxodeca-4,6-diene-5,6-diol and 2,2,9,9-tetramethyl-3,8-dioxodeca-4,6-diene-5,6-diol at various molar ratios of the reactants have been studied. Irrespective of the molar ratio, binuclear chelate complexes Ph4Sb[OC(R)CHC(O)(O)CCH(R)CO]SbPh4 are formed. The structures of the resulting complexes were established by the methods of IR and NMR spectroscopy.
About the authors
E. V. Artem’eva
National Research South Ural State University
Author for correspondence.
Email: katriona-art@yandex.ru
Russian Federation, pr. Lenina 76, Chelyabinsk, 454080
O. K. Sharutina
National Research South Ural State University
Email: katriona-art@yandex.ru
Russian Federation, pr. Lenina 76, Chelyabinsk, 454080
V. V. Sharutin
National Research South Ural State University
Email: katriona-art@yandex.ru
Russian Federation, pr. Lenina 76, Chelyabinsk, 454080