On the mechanism of cobalt(III) aminates pyrolysis

M. A. Ilyushin; Yu. S. Tverjanovich; A. S. Tverjanovich; A. O. Aver’yanov; A. V. Smirnov; I. V. Shugalei

doi:10.1134/S1070363217110147

On the mechanism of cobalt(III) aminates pyrolysis

Authors: Ilyushin M.A.¹, Tverjanovich Y.S.², Tverjanovich A.S.², Aver’yanov A.O.², Smirnov A.V.¹, Shugalei I.V.¹
Affiliations:
1. St. Petersburg State Technological Institute (Technical University)
2. St. Petersburg State University
Issue: Vol 87, No 11 (2017)
Pages: 2600-2604
Section: Article
URL: https://journals.rcsi.science/1070-3632/article/view/221580
DOI: https://doi.org/10.1134/S1070363217110147
ID: 221580

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Abstract

Pyrolysis of the complex (ato-N²)pentaammincobalt(III) perchlorate and the ligand 5-nitrotetrazole, and also of the initial complex aquapentaammincobalt(III) perchlorate was studied by the mass spectroscopy method. The leading oxidizer of ligands in the complexes is changed for the outer-sphere perchlorate ion at the pyrolysis temperature of ~250°C.