Stability of tetraoxides of chemical elements


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Abstract

Published data on the synthesis of eight-valence iridium and some other elements, and also works casting doubt on the fact of preparing iron and some 5f-elements in the oxidation state +8 were analyzed. Supposed methods (nuclear-chemical and pulse radiolysis methods) for Pu(VIII) and Am(VIII) detection and the method of matrix isolation at a temperature of 4–6 K for stabilization of eight-valence in Fe, Pu, and Am were considered.

About the authors

V. P. Shilov

A.N. Frumkin Institute of Physical Chemistry and Electrochemistry

Author for correspondence.
Email: ShilovV@ipc.rssi.ru
Russian Federation, Leninskii pr. 31/4, Moscow, 119071

A. M. Fedoseev

A.N. Frumkin Institute of Physical Chemistry and Electrochemistry

Email: ShilovV@ipc.rssi.ru
Russian Federation, Leninskii pr. 31/4, Moscow, 119071

A. V. Gogolev

A.N. Frumkin Institute of Physical Chemistry and Electrochemistry

Email: ShilovV@ipc.rssi.ru
Russian Federation, Leninskii pr. 31/4, Moscow, 119071


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