Stability of tetraoxides of chemical elements
- Authors: Shilov V.P.1, Fedoseev A.M.1, Gogolev A.V.1
-
Affiliations:
- A.N. Frumkin Institute of Physical Chemistry and Electrochemistry
- Issue: Vol 87, No 10 (2017)
- Pages: 2265-2268
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/221390
- DOI: https://doi.org/10.1134/S1070363217100036
- ID: 221390
Cite item
Abstract
Published data on the synthesis of eight-valence iridium and some other elements, and also works casting doubt on the fact of preparing iron and some 5f-elements in the oxidation state +8 were analyzed. Supposed methods (nuclear-chemical and pulse radiolysis methods) for Pu(VIII) and Am(VIII) detection and the method of matrix isolation at a temperature of 4–6 K for stabilization of eight-valence in Fe, Pu, and Am were considered.
About the authors
V. P. Shilov
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry
Author for correspondence.
Email: ShilovV@ipc.rssi.ru
Russian Federation, Leninskii pr. 31/4, Moscow, 119071
A. M. Fedoseev
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry
Email: ShilovV@ipc.rssi.ru
Russian Federation, Leninskii pr. 31/4, Moscow, 119071
A. V. Gogolev
A.N. Frumkin Institute of Physical Chemistry and Electrochemistry
Email: ShilovV@ipc.rssi.ru
Russian Federation, Leninskii pr. 31/4, Moscow, 119071