Structure, magnetic, and electrical properties of bismuth niobates doped with d-elements: XVII.1 Magnetic properties of Bi5Nb3–3xMn3xO15–δ solid solutions
- Authors: Chezhina N.V.1, Korolev D.A.1, Fedorova A.V.1, Zhuk N.A.2, Filippova M.V.2, Feltsinger L.S.2, Lutoev V.P.3, Makeev B.A.3, Shevchuk S.S.3, Nizovtsev A.N.4
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Affiliations:
- St. Petersburg State University
- Syktyvkar State University
- Institute of Geology, Komi Scientific Center, Ural Branch
- Institute of Biology, Komi Scientific Center, Ural Branch
- Issue: Vol 87, No 10 (2017)
- Pages: 2251-2257
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/221386
- DOI: https://doi.org/10.1134/S1070363217100012
- ID: 221386
Cite item
Abstract
A monoclinic distortion of tetragonal cell was found in the solid solutions with layered perovskite-like structure [Bi5Nb3–3xMn3xO15–δ (0.005 < х ≤ 0.06)]. In the ESR spectra absorption bands with g-factors ~4.3 and 2.1 assigned to Mn(II) and Mn(IV) atoms are recorded. The studies of magnetic susceptibility of the Bi5Nb3–3xMn3xO15–δ solid solutions revealed the formation of ferro- and antiferromagnetically bonded dimers of Mn(II), Mn(III), and Mn(IV) atoms. The exchange parameters in dimers and the distribution of paramagnetic manganese atoms in dependence to solid solution concentrations were calculated.
About the authors
N. V. Chezhina
St. Petersburg State University
Author for correspondence.
Email: n.chezhina@spbu.ru
Russian Federation, Universitetskaya nab. 7–9, St. Petersburg, 199034
D. A. Korolev
St. Petersburg State University
Email: n.chezhina@spbu.ru
Russian Federation, Universitetskaya nab. 7–9, St. Petersburg, 199034
A. V. Fedorova
St. Petersburg State University
Email: n.chezhina@spbu.ru
Russian Federation, Universitetskaya nab. 7–9, St. Petersburg, 199034
N. A. Zhuk
Syktyvkar State University
Email: n.chezhina@spbu.ru
Russian Federation, Syktyvkar
M. V. Filippova
Syktyvkar State University
Email: n.chezhina@spbu.ru
Russian Federation, Syktyvkar
L. S. Feltsinger
Syktyvkar State University
Email: n.chezhina@spbu.ru
Russian Federation, Syktyvkar
V. P. Lutoev
Institute of Geology, Komi Scientific Center, Ural Branch
Email: n.chezhina@spbu.ru
Russian Federation, Syktyvkar
B. A. Makeev
Institute of Geology, Komi Scientific Center, Ural Branch
Email: n.chezhina@spbu.ru
Russian Federation, Syktyvkar
S. S. Shevchuk
Institute of Geology, Komi Scientific Center, Ural Branch
Email: n.chezhina@spbu.ru
Russian Federation, Syktyvkar
A. N. Nizovtsev
Institute of Biology, Komi Scientific Center, Ural Branch
Email: n.chezhina@spbu.ru
Russian Federation, Syktyvkar