Synthesis, acid‒base properties, and complexing properties of N,N-bis[butoxy(hydroxy)phosphinoylmethyl]glycine
- Authors: Shurygin I.D.1, Garifzyanov A.R.1, Cherkasov R.A.1
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Affiliations:
- Kazan Federal University
- Issue: Vol 87, No 8 (2017)
- Pages: 1882-1883
- Section: Letters to the Editor
- URL: https://journals.rcsi.science/1070-3632/article/view/221178
- DOI: https://doi.org/10.1134/S1070363217080394
- ID: 221178
Cite item
Abstract
N,N-Bis(dibutoxyphosphinoylmethyl)glycine was synthesized by the Kabachnik‒Fields reaction in the three-component system glycine hydrochloride–formaldehyde–dibutyl hydrogen phosphite. Saponification of the product gave N,N-bis[butoxy(hydroxy)phosphinoylmethyl]glycine as the normal potassium salt. pH-Metric titration was used to determine the ionization constants of N,N-bis[butoxy(hydroxy)phosphinoylmethyl]-glycine, аs well as the stability constants of its Mn(II), Co(II), Ni(II), Cu(II), and Zn(II) complexes.
About the authors
I. D. Shurygin
Kazan Federal University
Author for correspondence.
Email: idshurygin@gmail.com
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008
A. R. Garifzyanov
Kazan Federal University
Email: idshurygin@gmail.com
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008
R. A. Cherkasov
Kazan Federal University
Email: idshurygin@gmail.com
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008