Mechanochemical synthesis of vanadium(III) β-diketonates
- Authors: Makhaev V.D.1, Petrova L.A.1
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Affiliations:
- Institute of Problems of Chemical Physics
- Issue: Vol 87, No 6 (2017)
- Pages: 1105-1109
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/220114
- DOI: https://doi.org/10.1134/S1070363217060019
- ID: 220114
Cite item
Abstract
The effect of the mechanical treatment conditions and of the nature of reactants on the course of the solid-phase reaction of vanadium(III) chloride with sodium β-diketonates and potassium tetramethylheptanedionate, on the yield of the reaction products, and on some properties of the activated mixtures was examined. A method was developed for the synthesis of vanadium(III) β-diketonates by the solid-phase mechanochemical reaction of vanadium(III) chloride with appropriate sodium or potassium β-diketonate, followed by sublimation or extraction.
About the authors
V. D. Makhaev
Institute of Problems of Chemical Physics
Author for correspondence.
Email: vim@icp.ac.ru
Russian Federation, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432
L. A. Petrova
Institute of Problems of Chemical Physics
Email: vim@icp.ac.ru
Russian Federation, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432