Synthesis and complex formation of spirobenzopyranindolines containing rhodamine fragment
- Authors: Solovyova E.V.1, Rostovtseva I.A.1, Shepelenko K.E.1, Voloshin N.A.1, Chernyshev A.V.1, Borodkin G.S.1, Metelitsa A.V.1, Minkin V.I.1
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Affiliations:
- Research Institute of Physical and Organic Chemistry
- Issue: Vol 87, No 5 (2017)
- Pages: 1007-1014
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/219805
- DOI: https://doi.org/10.1134/S107036321705019X
- ID: 219805
Cite item
Abstract
The interaction of 7-hydroxy-6-formyl-substituted spiropyrans and Rhodamine B aminoethylamide has afforded spirobenzopyrans containing rhodamine fragment bound to the benzopyran part via the methyleneaminoethyl spacer. The prepared spiropyrans exist in the spiropyran-spirolactam form in the acetone solution and exhibit weak photochromism at 283 K. The addition of Cd, Co, Ni, and Zn perchlorates to the spiropyrans solution results in the coloration due to the complex formation. The composition and stability of the complexes has been determined by means of spectrophotometry.
Keywords
About the authors
E. V. Solovyova
Research Institute of Physical and Organic Chemistry
Author for correspondence.
Email: photo@ipoc.sfedu.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344090
I. A. Rostovtseva
Research Institute of Physical and Organic Chemistry
Email: photo@ipoc.sfedu.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344090
K. E. Shepelenko
Research Institute of Physical and Organic Chemistry
Email: photo@ipoc.sfedu.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344090
N. A. Voloshin
Research Institute of Physical and Organic Chemistry
Email: photo@ipoc.sfedu.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344090
A. V. Chernyshev
Research Institute of Physical and Organic Chemistry
Email: photo@ipoc.sfedu.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344090
G. S. Borodkin
Research Institute of Physical and Organic Chemistry
Email: photo@ipoc.sfedu.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344090
A. V. Metelitsa
Research Institute of Physical and Organic Chemistry
Email: photo@ipoc.sfedu.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344090
V. I. Minkin
Research Institute of Physical and Organic Chemistry
Email: photo@ipoc.sfedu.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344090