Synthesis of bicyclic diesters of malonic and succinic acids
- Authors: Mamedov M.K.1, Kerimova F.S.1, Ismailova J.G.1
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Affiliations:
- Yu.G. Mamedaliev Institute of Petrochemical Processes
- Issue: Vol 87, No 1 (2017)
- Pages: 13-15
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/217785
- DOI: https://doi.org/10.1134/S1070363217010030
- ID: 217785
Cite item
Abstract
Monoesters of malonic and succinic acids have been prepared in high yields by the BF3·OEt2-catalyzed addition of the acids to bicyclo[2.2.1]hept-2-ene. The synthesized monoesters were introduced in the reaction of esterification with saturated monoatomic alcohols С2–С7 in the presence of the KU-2-8 catalyst in the H-form, and the corresponding mixed diesters of dicarboxylic acids were obtained in high yields.
About the authors
M. K. Mamedov
Yu.G. Mamedaliev Institute of Petrochemical Processes
Author for correspondence.
Email: fax_8181@mail.ru
Azerbaijan, Khojaly pr. 30, Baku, 1025
F. S. Kerimova
Yu.G. Mamedaliev Institute of Petrochemical Processes
Email: fax_8181@mail.ru
Azerbaijan, Khojaly pr. 30, Baku, 1025
J. G. Ismailova
Yu.G. Mamedaliev Institute of Petrochemical Processes
Email: fax_8181@mail.ru
Azerbaijan, Khojaly pr. 30, Baku, 1025