Novel organoantimony compounds [2,6-(OMe)2C6H3]3SbO and [2,6-(OMe)2C6H3]3Sb(NCO)2·0.5(CH3)2CO. Synthesis and structure
- Authors: Egorova I.V.1, Zhidkov V.V.1, Grinishak I.P.1, Rodionova N.A.1
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Affiliations:
- Blagoveshchensk State Pedagogical University
- Issue: Vol 86, No 11 (2016)
- Pages: 2484-2491
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/216533
- DOI: https://doi.org/10.1134/S1070363216110141
- ID: 216533
Cite item
Abstract
Novel organic compounds of antimony(V), tris(2,6-dimethoxyphenyl)antimony diisocyanate and oxide, have been prepared and studied by X-ray diffraction analysis. Antimony atoms in the diisocyanate molecule and in two symmetrically independent molecules of the oxide exhibit trigonal-bipyramidal and tetrahedral coordination, respectively.
About the authors
I. V. Egorova
Blagoveshchensk State Pedagogical University
Author for correspondence.
Email: bgpu.chim.egorova@mail.ru
Russian Federation, ul. Lenina 104, Blagoveshchensk, 675000
V. V. Zhidkov
Blagoveshchensk State Pedagogical University
Email: bgpu.chim.egorova@mail.ru
Russian Federation, ul. Lenina 104, Blagoveshchensk, 675000
I. P. Grinishak
Blagoveshchensk State Pedagogical University
Email: bgpu.chim.egorova@mail.ru
Russian Federation, ul. Lenina 104, Blagoveshchensk, 675000
N. A. Rodionova
Blagoveshchensk State Pedagogical University
Email: bgpu.chim.egorova@mail.ru
Russian Federation, ul. Lenina 104, Blagoveshchensk, 675000