Novel organoantimony compounds [2,6-(OMe)2C6H3]3SbO and [2,6-(OMe)2C6H3]3Sb(NCO)2·0.5(CH3)2CO. Synthesis and structure


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Abstract

Novel organic compounds of antimony(V), tris(2,6-dimethoxyphenyl)antimony diisocyanate and oxide, have been prepared and studied by X-ray diffraction analysis. Antimony atoms in the diisocyanate molecule and in two symmetrically independent molecules of the oxide exhibit trigonal-bipyramidal and tetrahedral coordination, respectively.

About the authors

I. V. Egorova

Blagoveshchensk State Pedagogical University

Author for correspondence.
Email: bgpu.chim.egorova@mail.ru
Russian Federation, ul. Lenina 104, Blagoveshchensk, 675000

V. V. Zhidkov

Blagoveshchensk State Pedagogical University

Email: bgpu.chim.egorova@mail.ru
Russian Federation, ul. Lenina 104, Blagoveshchensk, 675000

I. P. Grinishak

Blagoveshchensk State Pedagogical University

Email: bgpu.chim.egorova@mail.ru
Russian Federation, ul. Lenina 104, Blagoveshchensk, 675000

N. A. Rodionova

Blagoveshchensk State Pedagogical University

Email: bgpu.chim.egorova@mail.ru
Russian Federation, ul. Lenina 104, Blagoveshchensk, 675000


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