Nafion-based composite solid electrolytes containing water-soluble fullerene C60 derivatives


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Abstract

Nafion-based composite solid polyelectrolytes containing fullerene C60 and its water-soluble derivatives fullerenol-C60 and tris-malonate-C60 were studied by the impedance spectroscopy method. It was found that introduction of these dopants in Nafion leads to a substantial increase in proton conductivity of the composites in the region of low relative humidity. The reasons for the influence of dopants on proton conductivity of composites were discussed.

About the authors

D. V. Postnov

St. Petersburg State University

Email: melnikova-n@yandex.ru
Russian Federation, Universitetskaya nab. 7–9, St. Petersburg, 199034

V. N. Postnov

St. Petersburg State University

Email: melnikova-n@yandex.ru
Russian Federation, Universitetskaya nab. 7–9, St. Petersburg, 199034

I. V. Murin

St. Petersburg State University

Email: melnikova-n@yandex.ru
Russian Federation, Universitetskaya nab. 7–9, St. Petersburg, 199034

N. A. Mel’nikova

St. Petersburg State University

Author for correspondence.
Email: melnikova-n@yandex.ru
Russian Federation, Universitetskaya nab. 7–9, St. Petersburg, 199034

K. N. Semenov

St. Petersburg State University

Email: melnikova-n@yandex.ru
Russian Federation, Universitetskaya nab. 7–9, St. Petersburg, 199034


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