Email this article Synthesis and association in dichloromethane solution of low-symmetry phenoxy(fluoro)-substituted nickel phthalocyaninates
- Authors: Koptyaev A.I.1, Galanin N.E.1, Shaposhnikov G.P.1
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Affiliations:
- Research Institute of Macroheterocyclic Compounds Chemistry
- Issue: Vol 86, No 4 (2016)
- Pages: 854-858
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/214640
- DOI: https://doi.org/10.1134/S1070363216040162
- ID: 214640
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Abstract
Cross-condensation of 4,5-diphenoxyphthalonitrile (component A) with tetrafluorophthalonitrile (component B) in the presence of nickel(II) acetate has yielded the low-symmetry nickel phthalocyaninates of the A3B, ABAB, and AABB types. Their spectral properties have been studied. It has been demonstrated that even at the concentration as low as (6.0–8.0) × 10–7 mol/L the examined complexes exist in the associated form in the dichloromethane solution.
About the authors
A. I. Koptyaev
Research Institute of Macroheterocyclic Compounds Chemistry
Email: nik-galanin@yandex.ru
Russian Federation, Sheremetevskii pr. 7, Ivanovo, 153000
N. E. Galanin
Research Institute of Macroheterocyclic Compounds Chemistry
Author for correspondence.
Email: nik-galanin@yandex.ru
Russian Federation, Sheremetevskii pr. 7, Ivanovo, 153000
G. P. Shaposhnikov
Research Institute of Macroheterocyclic Compounds Chemistry
Email: nik-galanin@yandex.ru
Russian Federation, Sheremetevskii pr. 7, Ivanovo, 153000
