Synthesis of benzothiazine sulfonamides via heteroatomic Diels–Alder reaction of para-fluoro-N-sulfinylaniline with bicyclo[2.2.1]heptenes
- Authors: Veremeichik Y.V.1, Shurpik D.N.2, Lodochnikova O.A.3, Plemenkov V.V.1
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Affiliations:
- Immanuel Kant Baltic Federal University
- Kazan (Volga) Federal University
- Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
- Issue: Vol 86, No 2 (2016)
- Pages: 296-299
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/213732
- DOI: https://doi.org/10.1134/S1070363216020158
- ID: 213732
Cite item
Abstract
Reaction of 4-fluoro-N-sulfinylaniline with norbornene and norbornadiene has afforded the Diels–Alder adducts of benzothiazine structure that have been oxidized into the corresponding benzothiazine sulfonamides. Structure of the obtained compounds and stereochemistry of the diene addition and epoxidation of norbornene olefin bonds have established by means of X-ray diffraction method.
About the authors
Ya. V. Veremeichik
Immanuel Kant Baltic Federal University
Author for correspondence.
Email: olga@iopc.ru
Russian Federation, Kaliningrad
D. N. Shurpik
Kazan (Volga) Federal University
Email: olga@iopc.ru
Russian Federation, Kazan, Tatarstan
O. A. Lodochnikova
Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
Email: olga@iopc.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
V. V. Plemenkov
Immanuel Kant Baltic Federal University
Email: olga@iopc.ru
Russian Federation, Kaliningrad