Magnetism and Photocatalytic Degradation of Organic Dyes Based on a New Metal Formate Framework


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Resumo

A new MOF of [Co(HCOO)2] · 0.33DMF (I) was prepared and characterized by IR, powder X-ray diffraction, and single-crystal X-ray diffraction (CIF file CCDC no. 1571166). Complex I exhibits a diamond framework based on Co-centered CoCo4 tetrahedral nodes, in which all metal ions have octahedral coordination geometry and all HCOO groups link the metal ions in syn-syn/anti modes. The magnetic property shows a main antiferromagnetic interaction and the ferromagnetic phase transition below 2 K. Furthermore, the photocatalytic properties of I for degradation of the methyl violet and Rhodamine B have been explored.

Sobre autores

F. Wang

Department of Chemistry and Chemical Engineering

Email: maqandght@126.com
República Popular da China, Xian

B. Li

Key Laboratory for Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology, School of Pharmacy

Email: maqandght@126.com
República Popular da China, Dongguan, 523808

Z. Luo

Key Laboratory for Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology, School of Pharmacy

Email: maqandght@126.com
República Popular da China, Dongguan, 523808

J. Liu

Key Laboratory for Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology, School of Pharmacy

Email: maqandght@126.com
República Popular da China, Dongguan, 523808

H. Sakiyama

Department of Material and Biological Chemistry, Faculty of Science

Email: maqandght@126.com
Japão, Kojirakawa, Yamagata, 990-8560

A. Ma

Key Laboratory for Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology, School of Pharmacy

Autor responsável pela correspondência
Email: maqandght@126.com
República Popular da China, Dongguan, 523808

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