Email this article Magnetism and Photocatalytic Degradation of Organic Dyes Based on a New Metal Formate Framework
- Authors: Wang F.M.1, Li B.H.2, Luo Z.D.2, Liu J.Q.2, Sakiyama H.3, Ma A.Q.2
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Affiliations:
- Department of Chemistry and Chemical Engineering
- Key Laboratory for Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology, School of Pharmacy
- Department of Material and Biological Chemistry, Faculty of Science
- Issue: Vol 44, No 7 (2018)
- Pages: 415-420
- Section: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/214551
- DOI: https://doi.org/10.1134/S1070328418070011
- ID: 214551
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Abstract
A new MOF of [Co(HCOO)2] · 0.33DMF (I) was prepared and characterized by IR, powder X-ray diffraction, and single-crystal X-ray diffraction (CIF file CCDC no. 1571166). Complex I exhibits a diamond framework based on Co-centered CoCo4 tetrahedral nodes, in which all metal ions have octahedral coordination geometry and all HCOO groups link the metal ions in syn-syn/anti modes. The magnetic property shows a main antiferromagnetic interaction and the ferromagnetic phase transition below 2 K. Furthermore, the photocatalytic properties of I for degradation of the methyl violet and Rhodamine B have been explored.
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About the authors
F. M. Wang
Department of Chemistry and Chemical Engineering
Email: maqandght@126.com
China, Xian
B. H. Li
Key Laboratory for Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology, School of Pharmacy
Email: maqandght@126.com
China, Dongguan, 523808
Z. D. Luo
Key Laboratory for Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology, School of Pharmacy
Email: maqandght@126.com
China, Dongguan, 523808
J. Q. Liu
Key Laboratory for Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology, School of Pharmacy
Email: maqandght@126.com
China, Dongguan, 523808
H. Sakiyama
Department of Material and Biological Chemistry, Faculty of Science
Email: maqandght@126.com
Japan, Kojirakawa, Yamagata, 990-8560
A. Q. Ma
Key Laboratory for Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology, School of Pharmacy
Author for correspondence.
Email: maqandght@126.com
China, Dongguan, 523808
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