Magnetism and Photocatalytic Degradation of Organic Dyes Based on a New Metal Formate Framework


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详细

A new MOF of [Co(HCOO)2] · 0.33DMF (I) was prepared and characterized by IR, powder X-ray diffraction, and single-crystal X-ray diffraction (CIF file CCDC no. 1571166). Complex I exhibits a diamond framework based on Co-centered CoCo4 tetrahedral nodes, in which all metal ions have octahedral coordination geometry and all HCOO groups link the metal ions in syn-syn/anti modes. The magnetic property shows a main antiferromagnetic interaction and the ferromagnetic phase transition below 2 K. Furthermore, the photocatalytic properties of I for degradation of the methyl violet and Rhodamine B have been explored.

作者简介

F. Wang

Department of Chemistry and Chemical Engineering

Email: maqandght@126.com
中国, Xian

B. Li

Key Laboratory for Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology, School of Pharmacy

Email: maqandght@126.com
中国, Dongguan, 523808

Z. Luo

Key Laboratory for Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology, School of Pharmacy

Email: maqandght@126.com
中国, Dongguan, 523808

J. Liu

Key Laboratory for Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology, School of Pharmacy

Email: maqandght@126.com
中国, Dongguan, 523808

H. Sakiyama

Department of Material and Biological Chemistry, Faculty of Science

Email: maqandght@126.com
日本, Kojirakawa, Yamagata, 990-8560

A. Ma

Key Laboratory for Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology, School of Pharmacy

编辑信件的主要联系方式.
Email: maqandght@126.com
中国, Dongguan, 523808

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