Email this article Magnetism and Structure of a 3D Uncommon Pentanuclearcopper(II) Coordination Polymer
- Authors: Jin J.C.1, Zhong H.R.2, Ma A.Q.2, Huang Y.J.2, Qiu S.W.3, Liu J.Q.2, Luo M.M.2, Xu J.W.2, Wang Y.Y.4, Sakiyama H.S.5
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Affiliations:
- Anhui Provincial Laboratory of Biomimetic Sensor and Detecting Technology, West Anhui University
- Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology and School of Pharmacy, Guangdong Medical University
- School of Inspection Science, Guangdong Medical University
- Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Materials Science, Northwest University
- Department of Science, Faculty of Science, Yamagata University,
- Issue: Vol 44, No 11 (2018)
- Pages: 693-700
- Section: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/214181
- DOI: https://doi.org/10.1134/S1070328418110039
- ID: 214181
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Abstract
A 3D coordination polymer, [Na3KCu5(Tar)2(HTar)2(H2O)7] (I) (H2Tar = tartaric acid), was synthesized by the reaction of potassium sodium tartrate and Cu(NO3)2 and characterized by X-ray single crystal diffraction (СIF file CCDC no. 1575976). Complex I is built up in a shell-like manner based on inner two symmetry-related pentanuclear copper cores, the cores are surrounded by coordinated synchronously Na and K atoms, which shapes into 3D nanoporous architecture. Additionally, I exhibits antiferromagnetic behavior.
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About the authors
J. C. Jin
Anhui Provincial Laboratory of Biomimetic Sensor and Detecting Technology, West Anhui University
Author for correspondence.
Email: jcjgd2017@126.com
China, Anhui, 23701
H. R. Zhong
Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology and School of Pharmacy, Guangdong Medical University
Email: wyaoyuxb@126.com
China, Dongguan, 523808
A. Q. Ma
Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology and School of Pharmacy, Guangdong Medical University
Author for correspondence.
Email: maqandght@126.com
China, Dongguan, 523808
Y. J. Huang
Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology and School of Pharmacy, Guangdong Medical University
Email: wyaoyuxb@126.com
China, Dongguan, 523808
S. W. Qiu
School of Inspection Science, Guangdong Medical University
Email: wyaoyuxb@126.com
China, Dongguan, 523808
J. Q. Liu
Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology and School of Pharmacy, Guangdong Medical University
Email: wyaoyuxb@126.com
China, Dongguan, 523808
M. M. Luo
Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology and School of Pharmacy, Guangdong Medical University
Email: wyaoyuxb@126.com
China, Dongguan, 523808
J. W. Xu
Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology and School of Pharmacy, Guangdong Medical University
Email: wyaoyuxb@126.com
China, Dongguan, 523808
Y. Y. Wang
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Materials Science, Northwest University
Author for correspondence.
Email: wyaoyuxb@126.com
China, Xi’an, 710069
H. S. Sakiyama
Department of Science, Faculty of Science, Yamagata University,
Email: wyaoyuxb@126.com
Japan, Kojirakawa, Yamagata 990-8560
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