Magnetism and Structure of a 3D Uncommon Pentanuclearcopper(II) Coordination Polymer

  • 作者: Jin J.C.1, Zhong H.R.2, Ma A.Q.2, Huang Y.J.2, Qiu S.W.3, Liu J.Q.2, Luo M.M.2, Xu J.W.2, Wang Y.Y.4, Sakiyama H.S.5
  • 隶属关系:
    1. Anhui Provincial Laboratory of Biomimetic Sensor and Detecting Technology, West Anhui University
    2. Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology and School of Pharmacy, Guangdong Medical University
    3. School of Inspection Science, Guangdong Medical University
    4. Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Materials Science, Northwest University
    5. Department of Science, Faculty of Science, Yamagata University,
  • 期: 卷 44, 编号 11 (2018)
  • 页面: 693-700
  • 栏目: Article
  • URL: https://journals.rcsi.science/1070-3284/article/view/214181
  • DOI: https://doi.org/10.1134/S1070328418110039
  • ID: 214181

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详细

A 3D coordination polymer, [Na3KCu5(Tar)2(HTar)2(H2O)7] (I) (H2Tar = tartaric acid), was synthesized by the reaction of potassium sodium tartrate and Cu(NO3)2 and characterized by X-ray single crystal diffraction (СIF file CCDC no. 1575976). Complex I is built up in a shell-like manner based on inner two symmetry-related pentanuclear copper cores, the cores are surrounded by coordinated synchronously Na and K atoms, which shapes into 3D nanoporous architecture. Additionally, I exhibits antiferromagnetic behavior.

作者简介

J. Jin

Anhui Provincial Laboratory of Biomimetic Sensor and Detecting Technology, West Anhui University

编辑信件的主要联系方式.
Email: jcjgd2017@126.com
中国, Anhui, 23701

H. Zhong

Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology and School of Pharmacy, Guangdong Medical University

Email: wyaoyuxb@126.com
中国, Dongguan, 523808

A. Ma

Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology and School of Pharmacy, Guangdong Medical University

编辑信件的主要联系方式.
Email: maqandght@126.com
中国, Dongguan, 523808

Y. Huang

Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology and School of Pharmacy, Guangdong Medical University

Email: wyaoyuxb@126.com
中国, Dongguan, 523808

S. Qiu

School of Inspection Science, Guangdong Medical University

Email: wyaoyuxb@126.com
中国, Dongguan, 523808

J. Liu

Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology and School of Pharmacy, Guangdong Medical University

Email: wyaoyuxb@126.com
中国, Dongguan, 523808

M. Luo

Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology and School of Pharmacy, Guangdong Medical University

Email: wyaoyuxb@126.com
中国, Dongguan, 523808

J. Xu

Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology and School of Pharmacy, Guangdong Medical University

Email: wyaoyuxb@126.com
中国, Dongguan, 523808

Y. Wang

Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Materials Science, Northwest University

编辑信件的主要联系方式.
Email: wyaoyuxb@126.com
中国, Xi’an, 710069

H. Sakiyama

Department of Science, Faculty of Science, Yamagata University,

Email: wyaoyuxb@126.com
日本, Kojirakawa, Yamagata 990-8560

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