Magnetism and Structure of a 3D Uncommon Pentanuclearcopper(II) Coordination Polymer

  • Авторлар: Jin J.C.1, Zhong H.R.2, Ma A.Q.2, Huang Y.J.2, Qiu S.W.3, Liu J.Q.2, Luo M.M.2, Xu J.W.2, Wang Y.Y.4, Sakiyama H.S.5
  • Мекемелер:
    1. Anhui Provincial Laboratory of Biomimetic Sensor and Detecting Technology, West Anhui University
    2. Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology and School of Pharmacy, Guangdong Medical University
    3. School of Inspection Science, Guangdong Medical University
    4. Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Materials Science, Northwest University
    5. Department of Science, Faculty of Science, Yamagata University,
  • Шығарылым: Том 44, № 11 (2018)
  • Беттер: 693-700
  • Бөлім: Article
  • URL: https://journals.rcsi.science/1070-3284/article/view/214181
  • DOI: https://doi.org/10.1134/S1070328418110039
  • ID: 214181

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Тек жазылушылар үшін

Аннотация

A 3D coordination polymer, [Na3KCu5(Tar)2(HTar)2(H2O)7] (I) (H2Tar = tartaric acid), was synthesized by the reaction of potassium sodium tartrate and Cu(NO3)2 and characterized by X-ray single crystal diffraction (СIF file CCDC no. 1575976). Complex I is built up in a shell-like manner based on inner two symmetry-related pentanuclear copper cores, the cores are surrounded by coordinated synchronously Na and K atoms, which shapes into 3D nanoporous architecture. Additionally, I exhibits antiferromagnetic behavior.

Негізгі сөздер

Авторлар туралы

J. Jin

Anhui Provincial Laboratory of Biomimetic Sensor and Detecting Technology, West Anhui University

Хат алмасуға жауапты Автор.
Email: jcjgd2017@126.com
ҚХР, Anhui, 23701

H. Zhong

Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology and School of Pharmacy, Guangdong Medical University

Email: wyaoyuxb@126.com
ҚХР, Dongguan, 523808

A. Ma

Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology and School of Pharmacy, Guangdong Medical University

Хат алмасуға жауапты Автор.
Email: maqandght@126.com
ҚХР, Dongguan, 523808

Y. Huang

Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology and School of Pharmacy, Guangdong Medical University

Email: wyaoyuxb@126.com
ҚХР, Dongguan, 523808

S. Qiu

School of Inspection Science, Guangdong Medical University

Email: wyaoyuxb@126.com
ҚХР, Dongguan, 523808

J. Liu

Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology and School of Pharmacy, Guangdong Medical University

Email: wyaoyuxb@126.com
ҚХР, Dongguan, 523808

M. Luo

Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology and School of Pharmacy, Guangdong Medical University

Email: wyaoyuxb@126.com
ҚХР, Dongguan, 523808

J. Xu

Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology and School of Pharmacy, Guangdong Medical University

Email: wyaoyuxb@126.com
ҚХР, Dongguan, 523808

Y. Wang

Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Materials Science, Northwest University

Хат алмасуға жауапты Автор.
Email: wyaoyuxb@126.com
ҚХР, Xi’an, 710069

H. Sakiyama

Department of Science, Faculty of Science, Yamagata University,

Email: wyaoyuxb@126.com
Жапония, Kojirakawa, Yamagata 990-8560

Қосымша файлдар

Қосымша файлдар
Әрекет
1. JATS XML

© Pleiades Publishing, Ltd., 2018