Three metal complexes based on tetrazolyl ligands: Hydrothermal syntheses, crystal structures, and fluorescence properties


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Three new complexes based on 1-tetrazole-4-imidazole-benzene (Tibz), namely, [Cd(Tibz)2(H2O)2]n (I), [Mn(Tibz)2(H2O)4] · 2H2O (II) and [Co(Tibz)2(H2O)4] · 2H2O (III) have been synthesized through hydrothermal method and structurally characterized by element analyses, IR spectroscopy and single-crystal X-ray diffraction analyses (CIF files CCDC nos. 1443867 (I), 1443868 (II), 1443869 (III)). Single-crystal X-ray diffraction reveals that complex I is a 1D double-chain architecture, II and III are both mononuclear complexes. The results of single-crystal X-ray diffraction analyses indicate that the hydrogen bond and π··· π stacking exist in the complexes, which make great contribution to the stabilities of complexes IIII. The fluorescent properties of these complexes have also been studied in the solid state at room temperature.

作者简介

F. Wang

College of Chemistry and Molecular Engineering; Department of Chemistry

Email: ljp-zd@zzu.edu.cn
中国, Zhengzhou, Henan, 450001; Zhengzhou, Henan, 450014

C. Wu

College of Chemistry and Molecular Engineering

Email: ljp-zd@zzu.edu.cn
中国, Zhengzhou, Henan, 450001

X. Liang

College of Chemistry and Molecular Engineering

Email: ljp-zd@zzu.edu.cn
中国, Zhengzhou, Henan, 450001

M. Li

Zhengzhou Foreign Language High School

Email: ljp-zd@zzu.edu.cn
中国, Zhengzhou, Henan, 450001

J. Li

College of Chemistry and Molecular Engineering

编辑信件的主要联系方式.
Email: ljp-zd@zzu.edu.cn
中国, Zhengzhou, Henan, 450001

Z. Liu

College of Chemistry and Molecular Engineering

Email: ljp-zd@zzu.edu.cn
中国, Zhengzhou, Henan, 450001

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