Отправить статью по E-mail Three metal complexes based on tetrazolyl ligands: Hydrothermal syntheses, crystal structures, and fluorescence properties
- Авторы: Wang F.1,2, Wu C.J.1, Liang X.X.1, Li M.Y.3, Li J.P.1, Liu Z.Y.1
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Учреждения:
- College of Chemistry and Molecular Engineering
- Department of Chemistry
- Zhengzhou Foreign Language High School
- Выпуск: Том 42, № 12 (2016)
- Страницы: 789-796
- Раздел: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/213356
- DOI: https://doi.org/10.1134/S1070328416120071
- ID: 213356
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Аннотация
Three new complexes based on 1-tetrazole-4-imidazole-benzene (Tibz), namely, [Cd(Tibz)2(H2O)2]n (I), [Mn(Tibz)2(H2O)4] · 2H2O (II) and [Co(Tibz)2(H2O)4] · 2H2O (III) have been synthesized through hydrothermal method and structurally characterized by element analyses, IR spectroscopy and single-crystal X-ray diffraction analyses (CIF files CCDC nos. 1443867 (I), 1443868 (II), 1443869 (III)). Single-crystal X-ray diffraction reveals that complex I is a 1D double-chain architecture, II and III are both mononuclear complexes. The results of single-crystal X-ray diffraction analyses indicate that the hydrogen bond and π··· π stacking exist in the complexes, which make great contribution to the stabilities of complexes I–III. The fluorescent properties of these complexes have also been studied in the solid state at room temperature.
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Об авторах
F. Wang
College of Chemistry and Molecular Engineering; Department of Chemistry
Email: ljp-zd@zzu.edu.cn
Китай, Zhengzhou, Henan, 450001; Zhengzhou, Henan, 450014
C. Wu
College of Chemistry and Molecular Engineering
Email: ljp-zd@zzu.edu.cn
Китай, Zhengzhou, Henan, 450001
X. Liang
College of Chemistry and Molecular Engineering
Email: ljp-zd@zzu.edu.cn
Китай, Zhengzhou, Henan, 450001
M. Li
Zhengzhou Foreign Language High School
Email: ljp-zd@zzu.edu.cn
Китай, Zhengzhou, Henan, 450001
J. Li
College of Chemistry and Molecular Engineering
Автор, ответственный за переписку.
Email: ljp-zd@zzu.edu.cn
Китай, Zhengzhou, Henan, 450001
Z. Liu
College of Chemistry and Molecular Engineering
Email: ljp-zd@zzu.edu.cn
Китай, Zhengzhou, Henan, 450001
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