Mononuclear Sb(V) Bromide Complexes with 3-Halopyridinium Cations: Synthesis, Structures, and Thermal Stability

S. A. Adonin; M. A. Bondarenko; P. A. Abramov; I. V. Korolkov; P. E. Plyusnin; M. N. Sokolov; V. P. Fedin

doi:10.1134/S1070328419020027

Mononuclear Sb(V) Bromide Complexes with 3-Halopyridinium Cations: Synthesis, Structures, and Thermal Stability

Autores: Adonin S.A.¹^,2, Bondarenko M.A.², Abramov P.A.¹^,2, Korolkov I.V.¹^,2, Plyusnin P.E.¹^,2, Sokolov M.¹^,3, Fedin V.P.¹^,2
Afiliações:
1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
2. Novosibirsk State University
3. Kazan (Volga Region) Federal University
Edição: Volume 45, Nº 2 (2019)
Páginas: 128-132
Seção: Article
URL: https://journals.rcsi.science/1070-3284/article/view/214633
DOI: https://doi.org/10.1134/S1070328419020027
ID: 214633

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Mononuclear complexes (3-XPyH)[SbBr₆] (X = Cl (I), Br (II)) are synthesized by the reactions of Sb₂O₃, Br₂, and 3-XPy in HBr. Compound I is characterized by X-ray structure analysis (СIF file CCDC no. 1818602). The crystals of compounds I and II are isostructural. The thermal stability of the synthesized complexes is studied by thermogravimetry.