Email this article Mononuclear Sb(V) Bromide Complexes with 3-Halopyridinium Cations: Synthesis, Structures, and Thermal Stability
- Authors: Adonin S.A.1,2, Bondarenko M.A.2, Abramov P.A.1,2, Korolkov I.V.1,2, Plyusnin P.E.1,2, Sokolov M.1,3, Fedin V.P.1,2
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Affiliations:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
- Novosibirsk State University
- Kazan (Volga Region) Federal University
- Issue: Vol 45, No 2 (2019)
- Pages: 128-132
- Section: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/214633
- DOI: https://doi.org/10.1134/S1070328419020027
- ID: 214633
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Abstract
Mononuclear complexes (3-XPyH)[SbBr6] (X = Cl (I), Br (II)) are synthesized by the reactions of Sb2O3, Br2, and 3-XPy in HBr. Compound I is characterized by X-ray structure analysis (СIF file CCDC no. 1818602). The crystals of compounds I and II are isostructural. The thermal stability of the synthesized complexes is studied by thermogravimetry.
About the authors
S. A. Adonin
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University
Author for correspondence.
Email: adonin@niic.nsc.ru
Russian Federation, Novosibirsk, 630090 ; Novosibirsk, 630090
M. A. Bondarenko
Novosibirsk State University
Email: adonin@niic.nsc.ru
Russian Federation, Novosibirsk, 630090
P. A. Abramov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University
Email: adonin@niic.nsc.ru
Russian Federation, Novosibirsk, 630090 ; Novosibirsk, 630090
I. V. Korolkov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University
Email: adonin@niic.nsc.ru
Russian Federation, Novosibirsk, 630090 ; Novosibirsk, 630090
P. E. Plyusnin
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University
Email: adonin@niic.nsc.ru
Russian Federation, Novosibirsk, 630090 ; Novosibirsk, 630090
M. N. Sokolov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Kazan (Volga Region) Federal University
Email: adonin@niic.nsc.ru
Russian Federation, Novosibirsk, 630090 ; Kazan
V. P. Fedin
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University
Email: adonin@niic.nsc.ru
Russian Federation, Novosibirsk, 630090 ; Novosibirsk, 630090
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