Crystal structures of the polymer copper(II) complexes with acylhydrazones of bromosalicylaldehyde derivatives

L. D. Popov; S. I. Levchenkov; I. N. Shcherbakov; K. Yu. Suponitskii; V. V. Lukov; V. A. Kogan

doi:10.1134/S1070328416020068

Crystal structures of the polymer copper(II) complexes with acylhydrazones of bromosalicylaldehyde derivatives

Autores: Popov L.D.¹, Levchenkov S.I.², Shcherbakov I.N.¹, Suponitskii K.Y.³, Lukov V.V.¹, Kogan V.A.¹
Afiliações:
1. Southern Federal University
2. Southern Scientific Center
3. Nesmeyanov Institute of Organoelement Compounds
Edição: Volume 42, Nº 3 (2016)
Páginas: 151-156
Seção: Article
URL: https://journals.rcsi.science/1070-3284/article/view/213380
DOI: https://doi.org/10.1134/S1070328416020068
ID: 213380

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Polymer copper(II) complexes with 5-bromosalicylaldehyde heptanoylhydrazone (I) and 3,5-dibromosalicylaldehyde acetylhydrazone (II) are synthesized and structurally characterized. In complex I, the formation of the polymer is due to the coordination of the hydrazide nitrogen atom to the copper(II) ion of the adjacent fragment. In complex II, polymer formation is due to the binding of the monomer fragments by dipyridyl linkers (CIF files CCDC 947908 (I) and 947909 (II)).