Crystal structures of the polymer copper(II) complexes with acylhydrazones of bromosalicylaldehyde derivatives


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Abstract

Polymer copper(II) complexes with 5-bromosalicylaldehyde heptanoylhydrazone (I) and 3,5-dibromosalicylaldehyde acetylhydrazone (II) are synthesized and structurally characterized. In complex I, the formation of the polymer is due to the coordination of the hydrazide nitrogen atom to the copper(II) ion of the adjacent fragment. In complex II, polymer formation is due to the binding of the monomer fragments by dipyridyl linkers (CIF files CCDC 947908 (I) and 947909 (II)).

About the authors

L. D. Popov

Southern Federal University

Email: s.levchenkov@gmail.com
Russian Federation, Rostov-on-Don, 344104

S. I. Levchenkov

Southern Scientific Center

Author for correspondence.
Email: s.levchenkov@gmail.com
Russian Federation, Rostov-on-Don

I. N. Shcherbakov

Southern Federal University

Email: s.levchenkov@gmail.com
Russian Federation, Rostov-on-Don, 344104

K. Yu. Suponitskii

Nesmeyanov Institute of Organoelement Compounds

Email: s.levchenkov@gmail.com
Russian Federation, ul. Vavilova 28, Moscow, 119991

V. V. Lukov

Southern Federal University

Email: s.levchenkov@gmail.com
Russian Federation, Rostov-on-Don, 344104

V. A. Kogan

Southern Federal University

Email: s.levchenkov@gmail.com
Russian Federation, Rostov-on-Don, 344104

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