Email this article Polymer chlorobismuthate complex catena-{((Me,Me)Bpe)[BiCl5]}n: Synthesis and crystal structure
- Authors: Adonin S.A.1,2, Samsonenko D.G.1,2, Sokolov M.N.1,2, Fedin V.P.1,2
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Affiliations:
- Nikolaev Institute of Inorganic Chemistry
- Novosibirsk State University
- Issue: Vol 42, No 1 (2016)
- Pages: 27-31
- Section: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/213365
- DOI: https://doi.org/10.1134/S1070328416010012
- ID: 213365
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Abstract
The reaction of BiCl3 and N,N-dimethyl-1,2-bis(pyridyl)ethane chloride (Me,Me-Bpe) in 2 M HCl affords a polymer chlorobismuthate complex {((Me,Me)Bpe)[BiCl5]}n (I). The structure of complex I is determined by X-ray diffraction analysis (CIF file CCDC 1058842). The anionic moiety of the complex is presented by a 1D coordination polymer ([BiCl5]2n–)n consisting of octahedral blocks {Cl6} linked by µ2- bridging chloride ligands into infinite zigzag chains.
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About the authors
S. A. Adonin
Nikolaev Institute of Inorganic Chemistry; Novosibirsk State University
Author for correspondence.
Email: adonin@niic.nsc.ru
Russian Federation, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090; ul. Pirogova 2, Novosibirsk, 630090
D. G. Samsonenko
Nikolaev Institute of Inorganic Chemistry; Novosibirsk State University
Email: adonin@niic.nsc.ru
Russian Federation, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090; ul. Pirogova 2, Novosibirsk, 630090
M. N. Sokolov
Nikolaev Institute of Inorganic Chemistry; Novosibirsk State University
Email: adonin@niic.nsc.ru
Russian Federation, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090; ul. Pirogova 2, Novosibirsk, 630090
V. P. Fedin
Nikolaev Institute of Inorganic Chemistry; Novosibirsk State University
Email: adonin@niic.nsc.ru
Russian Federation, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090; ul. Pirogova 2, Novosibirsk, 630090
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