Enviar artigo por via de e-mail Polymer chlorobismuthate complex catena-{((Me,Me)Bpe)[BiCl5]}n: Synthesis and crystal structure
- Autores: Adonin S.A.1,2, Samsonenko D.G.1,2, Sokolov M.N.1,2, Fedin V.P.1,2
-
Afiliações:
- Nikolaev Institute of Inorganic Chemistry
- Novosibirsk State University
- Edição: Volume 42, Nº 1 (2016)
- Páginas: 27-31
- Seção: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/213365
- DOI: https://doi.org/10.1134/S1070328416010012
- ID: 213365
Citar
Acesso aberto
Acesso está concedido
Somente assinantes
Resumo
The reaction of BiCl3 and N,N-dimethyl-1,2-bis(pyridyl)ethane chloride (Me,Me-Bpe) in 2 M HCl affords a polymer chlorobismuthate complex {((Me,Me)Bpe)[BiCl5]}n (I). The structure of complex I is determined by X-ray diffraction analysis (CIF file CCDC 1058842). The anionic moiety of the complex is presented by a 1D coordination polymer ([BiCl5]2n–)n consisting of octahedral blocks {Cl6} linked by µ2- bridging chloride ligands into infinite zigzag chains.
Palavras-chave
Sobre autores
S. Adonin
Nikolaev Institute of Inorganic Chemistry; Novosibirsk State University
Autor responsável pela correspondência
Email: adonin@niic.nsc.ru
Rússia, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090; ul. Pirogova 2, Novosibirsk, 630090
D. Samsonenko
Nikolaev Institute of Inorganic Chemistry; Novosibirsk State University
Email: adonin@niic.nsc.ru
Rússia, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090; ul. Pirogova 2, Novosibirsk, 630090
M. Sokolov
Nikolaev Institute of Inorganic Chemistry; Novosibirsk State University
Email: adonin@niic.nsc.ru
Rússia, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090; ul. Pirogova 2, Novosibirsk, 630090
V. Fedin
Nikolaev Institute of Inorganic Chemistry; Novosibirsk State University
Email: adonin@niic.nsc.ru
Rússia, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090; ul. Pirogova 2, Novosibirsk, 630090
Arquivos suplementares
