Email this article Synthesis, Crystal Structure, and Electrochemical Properties of One Polyoxometalate-Based Silver(I) Compound with Keggin-Type [PW12O40]3− Anions
- Authors: Yang H.X.1, Zhu W.J.1, Jin L.Y.1, Bai Y.1, Dang D.B.1
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Affiliations:
- Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering
- Issue: Vol 44, No 7 (2018)
- Pages: 466-472
- Section: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/214578
- DOI: https://doi.org/10.1134/S1070328418070035
- ID: 214578
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Abstract
One polyoxometalate-based silver(I) compound [Ag(2,2'-Bipy)2]3(PW12O40) (I) (2,2'-Bipy = 2,2'- bipyridine) has been synthesized and structurally characterized by IR spectroscopy, elemental analysis, XRPD and X-ray single-crystal structure analysis (CIF file CCDC no. 1572216). Compound I exhibits a crystalline three-dimentional supramolecular framework constructed by Ag-2,2'-Bipy coordination units and [PW12O40]3− template anions, in which there are multiform π...π interactions and hydrogen bonds. The cyclic voltammetric experiments show that compound I displays a good electrocatalytic activity toward the reduction of nitrite.
About the authors
H. X. Yang
Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering
Email: baiyan@henu.edu.cn
China, Kaifeng, 475004
W. J. Zhu
Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering
Email: baiyan@henu.edu.cn
China, Kaifeng, 475004
L. Y. Jin
Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering
Email: baiyan@henu.edu.cn
China, Kaifeng, 475004
Y. Bai
Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering
Author for correspondence.
Email: baiyan@henu.edu.cn
China, Kaifeng, 475004
D. B. Dang
Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering
Email: baiyan@henu.edu.cn
China, Kaifeng, 475004
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