Отправить статью по E-mail Synthesis, Crystal Structure, and Electrochemical Properties of One Polyoxometalate-Based Silver(I) Compound with Keggin-Type [PW12O40]3− Anions
- Авторы: Yang H.X.1, Zhu W.J.1, Jin L.Y.1, Bai Y.1, Dang D.B.1
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Учреждения:
- Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering
- Выпуск: Том 44, № 7 (2018)
- Страницы: 466-472
- Раздел: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/214578
- DOI: https://doi.org/10.1134/S1070328418070035
- ID: 214578
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Аннотация
One polyoxometalate-based silver(I) compound [Ag(2,2'-Bipy)2]3(PW12O40) (I) (2,2'-Bipy = 2,2'- bipyridine) has been synthesized and structurally characterized by IR spectroscopy, elemental analysis, XRPD and X-ray single-crystal structure analysis (CIF file CCDC no. 1572216). Compound I exhibits a crystalline three-dimentional supramolecular framework constructed by Ag-2,2'-Bipy coordination units and [PW12O40]3− template anions, in which there are multiform π...π interactions and hydrogen bonds. The cyclic voltammetric experiments show that compound I displays a good electrocatalytic activity toward the reduction of nitrite.
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Об авторах
H. Yang
Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering
Email: baiyan@henu.edu.cn
Китай, Kaifeng, 475004
W. Zhu
Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering
Email: baiyan@henu.edu.cn
Китай, Kaifeng, 475004
L. Jin
Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering
Email: baiyan@henu.edu.cn
Китай, Kaifeng, 475004
Y. Bai
Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering
Автор, ответственный за переписку.
Email: baiyan@henu.edu.cn
Китай, Kaifeng, 475004
D. Dang
Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering
Email: baiyan@henu.edu.cn
Китай, Kaifeng, 475004
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