Email this article Yttrium complexes with 3,6-bis(tert-butylcatecholate)
- Authors: Petrov P.A.1,2, Samsonenko D.G.1,2
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Affiliations:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk State University
- Issue: Vol 43, No 8 (2017)
- Pages: 500-504
- Section: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/214004
- DOI: https://doi.org/10.1134/S1070328417080048
- ID: 214004
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Abstract
Heterometallic complex [K3Y(Cat36)3(Dme)4] (I) or binuclear complex [Y2(Cat36)3(Dme)3] · Dme (II · Dme) is synthesized, depending on the reactant ratio, by the reaction of YCl3 with 3,6-bis(tertbutylcatecholate) potassium salt (K2Cat36) in 1,2-dimethoxyethane (Dme). Both complexes are characterized by single-crystal X-ray diffraction analysis (CIF files CCDC nos. 1527929 (I) and 1527930 (II)) and 1H and 13C NMR spectroscopy.
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About the authors
P. A. Petrov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University
Author for correspondence.
Email: panah@niic.nsc.ru
Russian Federation, pr. akademika Lavrent’eva 3, Novosibirsk, 630090; ul. Pirogova 2, Novosibirsk, 630090
D. G. Samsonenko
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University
Email: panah@niic.nsc.ru
Russian Federation, pr. akademika Lavrent’eva 3, Novosibirsk, 630090; ul. Pirogova 2, Novosibirsk, 630090
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