A New Metalloligand Powerful in Forming Helical Coordination Polymers
- Авторы: Zhang S.Z.1, Yuan B.1, Lan Y.L.1, Li X.Z.1, Hao P.P.2, Zhu L.N.1
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Учреждения:
- Department of Chemistry, School of Science
- Department of Chemical Engineering
- Выпуск: Том 43, № 10 (2017)
- Страницы: 700-707
- Раздел: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/213591
- DOI: https://doi.org/10.1134/S1070328417100116
- ID: 213591
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Аннотация
A new macrocyclic oxamido carboxylate metalloligand was designed and three heteronuclear coordination polymers of the metalloligand and metal nodes Cu2+, Zn2+ and Cd2+ were prepared. X-ray single crystal analyses (CIF files CCDC nos. 1025722–1025724 for I–III) revealed that multiple favourable features endowed the metalloligand with a strong power to force the metal nodes to generate 1D helical coordination polymers. Thermogravimetric analyses showed that the complexes with Cu2+ and Zn2+ nodes exhibited moderate thermal stability. The three complexes were also characterized by IR spectra and PXRD.
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Об авторах
S. Zhang
Department of Chemistry, School of Science
Email: lixiaozeng321@tju.edu.cn
Китай, Tianjin, 300072
B. Yuan
Department of Chemistry, School of Science
Email: lixiaozeng321@tju.edu.cn
Китай, Tianjin, 300072
Y. Lan
Department of Chemistry, School of Science
Email: lixiaozeng321@tju.edu.cn
Китай, Tianjin, 300072
X. Li
Department of Chemistry, School of Science
Автор, ответственный за переписку.
Email: lixiaozeng321@tju.edu.cn
Китай, Tianjin, 300072
P. Hao
Department of Chemical Engineering
Email: lixiaozeng321@tju.edu.cn
Китай, Tianjin, 301636
L. Zhu
Department of Chemistry, School of Science
Email: lixiaozeng321@tju.edu.cn
Китай, Tianjin, 300072
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