A New Metalloligand Powerful in Forming Helical Coordination Polymers


Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Abstract

A new macrocyclic oxamido carboxylate metalloligand was designed and three heteronuclear coordination polymers of the metalloligand and metal nodes Cu2+, Zn2+ and Cd2+ were prepared. X-ray single crystal analyses (CIF files CCDC nos. 1025722–1025724 for I–III) revealed that multiple favourable features endowed the metalloligand with a strong power to force the metal nodes to generate 1D helical coordination polymers. Thermogravimetric analyses showed that the complexes with Cu2+ and Zn2+ nodes exhibited moderate thermal stability. The three complexes were also characterized by IR spectra and PXRD.

About the authors

S. Z. Zhang

Department of Chemistry, School of Science

Email: lixiaozeng321@tju.edu.cn
China, Tianjin, 300072

B. Yuan

Department of Chemistry, School of Science

Email: lixiaozeng321@tju.edu.cn
China, Tianjin, 300072

Y. L. Lan

Department of Chemistry, School of Science

Email: lixiaozeng321@tju.edu.cn
China, Tianjin, 300072

X. Z. Li

Department of Chemistry, School of Science

Author for correspondence.
Email: lixiaozeng321@tju.edu.cn
China, Tianjin, 300072

P. P. Hao

Department of Chemical Engineering

Email: lixiaozeng321@tju.edu.cn
China, Tianjin, 301636

L. N. Zhu

Department of Chemistry, School of Science

Email: lixiaozeng321@tju.edu.cn
China, Tianjin, 300072

Supplementary files

Supplementary Files
Action
1. JATS XML

Copyright (c) 2017 Pleiades Publishing, Ltd.