Email this article Synthesis, Characterization, and Crystal Structure of a Chiral Platinum(II) Complex with 2-(4-Methoxy-Phenyl)-Imidazo[4, 5-f][l,10]-Phenanthroline Binding Interaction with DNA
- Authors: Luo X.J.1, Wang S.L.1, Xu J.M.1, Yang Y.1, Luo Z.H.1, Liu R.J.1, Liang W.J.1
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Affiliations:
- Guangxi Key Laboratory of Farm Products Processing (Cultivation Base), Colleges and Universities Key Laboratory for Efficient Use of Agricultural Resources in the Southeast of Guangxi, College of Chemistry and Food Science
- Issue: Vol 43, No 10 (2017)
- Pages: 679-684
- Section: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/213570
- DOI: https://doi.org/10.1134/S1070328417100050
- ID: 213570
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Abstract
A new platinum(II) complex of [Pt(Chda)(4-MOPIP)]2+2Cl– · H2O (I) (Chda = cyclohexanediamine; 4-MOPIP = (4-methoxy-phenyl)-imidazo[4,5-f][l,10]-phenanthroline) has been synthesized by hydrothermal methods and characterized by elemental analysis, IR, single-crystal X-ray diffraction (CIF file CCDC no. 1472980), UV-Vis and fluorescent spectrum. In complex I, the platinum adopts a four-coordinated square planar geometry. The DNA-binding interaction has been investigated. The complex can bind to DNA by intercalative mode, presenting the high DNA-binding affinity.
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About the authors
X. J. Luo
Guangxi Key Laboratory of Farm Products Processing (Cultivation Base), Colleges and Universities Key Laboratory for Efficient Use of Agricultural Resources in the Southeast of Guangxi, College of Chemistry and Food Science
Email: yy135175@163.com
China, Yulin, 537000
S. L. Wang
Guangxi Key Laboratory of Farm Products Processing (Cultivation Base), Colleges and Universities Key Laboratory for Efficient Use of Agricultural Resources in the Southeast of Guangxi, College of Chemistry and Food Science
Email: yy135175@163.com
China, Yulin, 537000
J. M. Xu
Guangxi Key Laboratory of Farm Products Processing (Cultivation Base), Colleges and Universities Key Laboratory for Efficient Use of Agricultural Resources in the Southeast of Guangxi, College of Chemistry and Food Science
Email: yy135175@163.com
China, Yulin, 537000
Y. Yang
Guangxi Key Laboratory of Farm Products Processing (Cultivation Base), Colleges and Universities Key Laboratory for Efficient Use of Agricultural Resources in the Southeast of Guangxi, College of Chemistry and Food Science
Author for correspondence.
Email: yy135175@163.com
China, Yulin, 537000
Z. H. Luo
Guangxi Key Laboratory of Farm Products Processing (Cultivation Base), Colleges and Universities Key Laboratory for Efficient Use of Agricultural Resources in the Southeast of Guangxi, College of Chemistry and Food Science
Email: yy135175@163.com
China, Yulin, 537000
R. J. Liu
Guangxi Key Laboratory of Farm Products Processing (Cultivation Base), Colleges and Universities Key Laboratory for Efficient Use of Agricultural Resources in the Southeast of Guangxi, College of Chemistry and Food Science
Email: yy135175@163.com
China, Yulin, 537000
W. J. Liang
Guangxi Key Laboratory of Farm Products Processing (Cultivation Base), Colleges and Universities Key Laboratory for Efficient Use of Agricultural Resources in the Southeast of Guangxi, College of Chemistry and Food Science
Email: yy135175@163.com
China, Yulin, 537000
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