Mechanistic models of the ion-solvation shell system


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The eigenfrequencies of solvation shell oscillations with respect to the ion are estimated in various approximations describing the ion–solvation shell system. The results of comparisonwith experiments suggest that the most appropriate is the model in which the solvated ion is considered to be a spherical rotator formed either by the entire solvation shell or by a layer of solvent molecules adjacent to the outer boundary of the solvation shell.

Sobre autores

I. Shamanin

National Research Tomsk Polytechnic University, Nuclear Technologies Department

Autor responsável pela correspondência
Email: shiva@tpu.ru
Rússia, pr. Lenina 30, Tomsk, 634050

M. Kazaryan

Lebedev Physical Institute

Email: shiva@tpu.ru
Rússia, Leninskii pr. 53, Moscow, 119991

S. Timchenko

National Research Tomsk Polytechnic University, Nuclear Technologies Department

Email: shiva@tpu.ru
Rússia, pr. Lenina 30, Tomsk, 634050

I. Ushakov

National Research Tomsk Polytechnic University, Nuclear Technologies Department

Email: shiva@tpu.ru
Rússia, pr. Lenina 30, Tomsk, 634050

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