Email this article Mechanistic models of the ion-solvation shell system
- Authors: Shamanin I.V.1, Kazaryan M.A.2, Timchenko S.N.1, Ushakov I.A.1
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Affiliations:
- National Research Tomsk Polytechnic University, Nuclear Technologies Department
- Lebedev Physical Institute
- Issue: Vol 44, No 9 (2017)
- Pages: 254-257
- Section: Article
- URL: https://journals.rcsi.science/1068-3356/article/view/228442
- DOI: https://doi.org/10.3103/S1068335617090020
- ID: 228442
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Abstract
The eigenfrequencies of solvation shell oscillations with respect to the ion are estimated in various approximations describing the ion–solvation shell system. The results of comparisonwith experiments suggest that the most appropriate is the model in which the solvated ion is considered to be a spherical rotator formed either by the entire solvation shell or by a layer of solvent molecules adjacent to the outer boundary of the solvation shell.
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About the authors
I. V. Shamanin
National Research Tomsk Polytechnic University, Nuclear Technologies Department
Author for correspondence.
Email: shiva@tpu.ru
Russian Federation, pr. Lenina 30, Tomsk, 634050
M. A. Kazaryan
Lebedev Physical Institute
Email: shiva@tpu.ru
Russian Federation, Leninskii pr. 53, Moscow, 119991
S. N. Timchenko
National Research Tomsk Polytechnic University, Nuclear Technologies Department
Email: shiva@tpu.ru
Russian Federation, pr. Lenina 30, Tomsk, 634050
I. A. Ushakov
National Research Tomsk Polytechnic University, Nuclear Technologies Department
Email: shiva@tpu.ru
Russian Federation, pr. Lenina 30, Tomsk, 634050
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