Nitrosylsulfuric acid as a tandem reagent in the synthesis of 3,5-diarylisoxazoles from 1,2-diarylcyclopropanes

O. B. Bondarenko; A. I. Komarov; G. L. Karetnikov; S. N. Nikolaeva; N. V. Zyk

doi:10.1007/s11172-019-2540-1

Nitrosylsulfuric acid as a tandem reagent in the synthesis of 3,5-diarylisoxazoles from 1,2-diarylcyclopropanes

作者: Bondarenko O.¹, Komarov A.¹, Karetnikov G.¹, Nikolaeva S.¹, Zyk N.¹
隶属关系:
1. Department of Chemistry, M. V. Lomonosov Moscow State University
期: 卷 68, 编号 6 (2019)
页面: 1200-1203
栏目: Full Article
URL: https://journals.rcsi.science/1066-5285/article/view/243401
DOI: https://doi.org/10.1007/s11172-019-2540-1
ID: 243401

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It was demonstrated that nitrosylsulfuric acid can be successfully used as a tandem nitrosating and oxidizing agent in the synthesis of 3,5-diarylisoxazoles from 1,2-diarylcyclopropanes. The reaction proceeds highly regioselectively in the case of symmetric diarylcyclopropanes. The mixtures of regioisomeric 3,5-diarylisoxazoles were obtained from non-symmetric 1,2-diarylcyclopropanes.