A new approach to the study of the structure of polyisoprene obtained by cationic polymerization
- 作者: Rozentsvet V.A.1, Kozlov V.G.1, Stotskaya O.A.1, Smirnov S.N.2, Tolstoy P.M.2
-
隶属关系:
- Institute of Ecology of the Volga River Basin, Russian Academy of Sciences
- St.-Petersburg State University, Department of Chemistry
- 期: 卷 68, 编号 1 (2019)
- 页面: 116-120
- 栏目: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/243286
- DOI: https://doi.org/10.1007/s11172-019-2425-3
- ID: 243286
如何引用文章
详细
The use of the T2 filter in NMR studies allowed us to separate carbon atoms by their mobility in different fragments of the macromolecular chain of polyisoprene synthesized by cationic polymerization. The NMR signals of terminal units with conjugated double bonds were identified for the first time for the “cationic” polyisoprene, which experimentally confirmed the transfer of the growing chain to the monomer in the process of cationic polymerization of isoprene.
作者简介
V. Rozentsvet
Institute of Ecology of the Volga River Basin, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: rozentsvet@mail.ru
俄罗斯联邦, 10 ul. Komzina, Togliatti, 445003
V. Kozlov
Institute of Ecology of the Volga River Basin, Russian Academy of Sciences
Email: rozentsvet@mail.ru
俄罗斯联邦, 10 ul. Komzina, Togliatti, 445003
O. Stotskaya
Institute of Ecology of the Volga River Basin, Russian Academy of Sciences
Email: rozentsvet@mail.ru
俄罗斯联邦, 10 ul. Komzina, Togliatti, 445003
S. Smirnov
St.-Petersburg State University, Department of Chemistry
Email: rozentsvet@mail.ru
俄罗斯联邦, 7–9 Universitetskaya nab., St.-Petersburg, 199034
P. Tolstoy
St.-Petersburg State University, Department of Chemistry
Email: rozentsvet@mail.ru
俄罗斯联邦, 7–9 Universitetskaya nab., St.-Petersburg, 199034
补充文件
