Supramolecular organization of crown- and phosphoryl-containing magnesium and zinc phthalocyaninates in solutions of synthetic and natural surfactants
- 作者: Goldshleger N.1, Gak V.1, Lapshina M.1,2, Baulin V.3,4, Shiryaev A.3, Tsivadze A.3
-
隶属关系:
- Institute of Problems of Chemical Physics, Russian Academy of Sciences
- Moscow Region State University
- A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
- Institute of Physiologically Active Compounds, Russian Academy of Sciences
- 期: 卷 67, 编号 12 (2018)
- 页面: 2205-2211
- 栏目: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/243218
- DOI: https://doi.org/10.1007/s11172-018-2357-3
- ID: 243218
如何引用文章
详细
The behavior of crown- and phosphoryl-containing magnesium and zinc phthalocyaninates in solutions of synthetic and natural surfactants is studied. In a phosphate buffer (рН 7.4), zinc phthalocyaninate bearing oxy(pentyloxy)phosphoryl groups in peripheral substituents of the macrocycle is in aggregated state. According to absorption and fluorescence spectroscopy data, adding oppositely charged synthetic and natural surfactants leads to monomerization of this compound. The degree of monomerization of magnesium octa[(4´-benzo-15-crown-5)oxy]-phthalocyaninate in a microheterogeneous medium is affected by the concentration of sodium cholate and ionic strength. Fluorescence-active supramolecular gels based on sodium deoxycholate were prepared using phosphoryl-containing zinc phthalocyaninate.
作者简介
N. Goldshleger
Institute of Problems of Chemical Physics, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: nfgold@icp.ac.ru
俄罗斯联邦, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
V. Gak
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: mager1988@gmail.com
俄罗斯联邦, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
M. Lapshina
Institute of Problems of Chemical Physics, Russian Academy of Sciences; Moscow Region State University
Email: mager1988@gmail.com
俄罗斯联邦, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432; 10А ul. Radio, Moscow, 105005
V. Baulin
A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences; Institute of Physiologically Active Compounds, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: mager1988@gmail.com
俄罗斯联邦, Building 4, 31 Leninsky prosp., Moscow, 119071; 1 Severnyj proezd, Chernogolovka, Moscow Region, 142432
A. Shiryaev
A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: mager1988@gmail.com
俄罗斯联邦, Building 4, 31 Leninsky prosp., Moscow, 119071
A. Tsivadze
A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: mager1988@gmail.com
俄罗斯联邦, Building 4, 31 Leninsky prosp., Moscow, 119071