Polynuclear Ni II  and Co II  hexafluoroacetylacetonates

O. V. Kuznetsova; E. Yu. Fursova; G. A. Letyagin; G. V. Romanenko; V. I. Ovcharenko

doi:10.1007/s11172-018-2202-8

Polynuclear Ni^II and Co^II hexafluoroacetylacetonates

作者: Kuznetsova O.V.¹, Fursova E.Y.¹, Letyagin G.A.¹^,2, Romanenko G.V.¹, Ovcharenko V.I.¹
隶属关系:
1. International Tomography Center, Russian Academy of Sciences
2. Novosibirsk State University
期: 卷 67, 编号 7 (2018)
页面: 1202-1205
栏目: Article
URL: https://journals.rcsi.science/1066-5285/article/view/242684
DOI: https://doi.org/10.1007/s11172-018-2202-8
ID: 242684

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Hydrolysis of [M₄(hfac)₄(MeO)₄(MeOH)₄] (М = Сo, Ni and hfac is hexafluoroacetylaceton ate) is a convenient way of obtaining polynuclear complexes [Ni₇(hfac)₆(OH)₈(H₂O)₆]•2H₂O, [Co₁₂(hfac)₁₀(OH)₁₄(H₂O)₈]•2H₂O•2MePh, [Co₁₂(hfac)₁₀(OH)₁₄(H₂O)₄(Me₂CO)₄]•3PhMe, and [Co₁₂(hfac)₁₀(OH)₁₄(H₂O)₆(Me₂CO)₂]•2H₂O•2Me₂CO, whose structures were confirmed by X-ray analysis.