A mechanistic study of arabinigalactan sulfation with potassium persulfate in dimethyl sulfoxide


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The mechanism of polysaccharide arabinogalactan sulfation was studied. Potassium persulfate in dimethyl sulfoxide was used as a sulfating agent. Sulfation of the biopolymer proceeds via its reaction with the SO3—DMSO complex, which is formed upon the reduction of the persulfate anion in DMSO.

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Ya. Kostyro

A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

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Email: yanakos@irioch.irk.ru
俄罗斯联邦, 1 ul. Favorskogo, Irkutsk, 664033

V. Smirnov

A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Email: yanakos@irioch.irk.ru
俄罗斯联邦, 1 ul. Favorskogo, Irkutsk, 664033

L. Sinegovskaya

A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Email: yanakos@irioch.irk.ru
俄罗斯联邦, 1 ul. Favorskogo, Irkutsk, 664033

T. Vakul’skaya

A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Email: yanakos@irioch.irk.ru
俄罗斯联邦, 1 ul. Favorskogo, Irkutsk, 664033

S. Khutsishvili

A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Email: yanakos@irioch.irk.ru
俄罗斯联邦, 1 ul. Favorskogo, Irkutsk, 664033

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