A mechanistic study of arabinigalactan sulfation with potassium persulfate in dimethyl sulfoxide


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The mechanism of polysaccharide arabinogalactan sulfation was studied. Potassium persulfate in dimethyl sulfoxide was used as a sulfating agent. Sulfation of the biopolymer proceeds via its reaction with the SO3—DMSO complex, which is formed upon the reduction of the persulfate anion in DMSO.

Sobre autores

Ya. Kostyro

A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Autor responsável pela correspondência
Email: yanakos@irioch.irk.ru
Rússia, 1 ul. Favorskogo, Irkutsk, 664033

V. Smirnov

A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Email: yanakos@irioch.irk.ru
Rússia, 1 ul. Favorskogo, Irkutsk, 664033

L. Sinegovskaya

A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Email: yanakos@irioch.irk.ru
Rússia, 1 ul. Favorskogo, Irkutsk, 664033

T. Vakul’skaya

A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Email: yanakos@irioch.irk.ru
Rússia, 1 ul. Favorskogo, Irkutsk, 664033

S. Khutsishvili

A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Email: yanakos@irioch.irk.ru
Rússia, 1 ul. Favorskogo, Irkutsk, 664033

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