Synthesis and molecular structure of a manganese tricarbonyl complex based on 5,6- nido -C 2 B 8 H 12  carborane

A. I. Lazareva; I. V. Pisareva; E. V. Balagurova; A. F. Smolyakov; F. M. Dolgushin; I. A. Godovikov; I. T. Chizhevsky

doi:10.1007/s11172-017-1994-2

Synthesis and molecular structure of a manganese tricarbonyl complex based on 5,6-nido-C₂B₈H₁₂ carborane

作者: Lazareva A.¹, Pisareva I.¹, Balagurova E.¹, Smolyakov A.¹^,2, Dolgushin F.¹, Godovikov I.¹, Chizhevsky I.¹
隶属关系:
1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
2. Faculty of Physics and Mathematics and Natural Sciences, Peoples’ Friendship University of Russia
期: 卷 66, 编号 11 (2017)
页面: 2142-2144
栏目: Full Article
URL: https://journals.rcsi.science/1066-5285/article/view/241643
DOI: https://doi.org/10.1007/s11172-017-1994-2
ID: 241643

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The anionic manganese tricarbonyl complex [1,1,1-(CO)₃-isonido-1,2,4-MnC₂B₈H₁₀]–was synthesized in the form of PPN and tmdaH salts (PPN is bis(triphenylphosphine)iminium, tmda is N,N,N’,N’-tetramethyl-1,8-diaminonaphthalene) by the reaction of the deprotonated form of the medium-size non-icosahedral carborane 5,6-nido-C₂B₈H₁₂ with Mn(CO)₅Br. The structure of the complex [tmdaH][1,1,1-(CO)₃-isonido-1,2,4-MnC₂B₈H₁₀] was deter-mined by X-ray diffraction.