Synthesis and molecular structure of a manganese tricarbonyl complex based on 5,6- nido -C 2 B 8 H 12  carborane

A. I. Lazareva; I. V. Pisareva; E. V. Balagurova; A. F. Smolyakov; F. M. Dolgushin; I. A. Godovikov; I. T. Chizhevsky

doi:10.1007/s11172-017-1994-2

Synthesis and molecular structure of a manganese tricarbonyl complex based on 5,6-nido-C₂B₈H₁₂ carborane

Авторы: Lazareva A.I.¹, Pisareva I.V.¹, Balagurova E.V.¹, Smolyakov A.F.¹^,2, Dolgushin F.M.¹, Godovikov I.A.¹, Chizhevsky I.T.¹
Учреждения:
1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
2. Faculty of Physics and Mathematics and Natural Sciences, Peoples’ Friendship University of Russia
Выпуск: Том 66, № 11 (2017)
Страницы: 2142-2144
Раздел: Full Article
URL: https://journals.rcsi.science/1066-5285/article/view/241643
DOI: https://doi.org/10.1007/s11172-017-1994-2
ID: 241643

Цитировать

Полный текст

Открытый доступ
Доступ закрыт

Доступ предоставлен
Доступ закрыт

Только для подписчиков

Аннотация
Об авторах
Список литературы
Дополнительные файлы
Статистика

Аннотация

The anionic manganese tricarbonyl complex [1,1,1-(CO)₃-isonido-1,2,4-MnC₂B₈H₁₀]–was synthesized in the form of PPN and tmdaH salts (PPN is bis(triphenylphosphine)iminium, tmda is N,N,N’,N’-tetramethyl-1,8-diaminonaphthalene) by the reaction of the deprotonated form of the medium-size non-icosahedral carborane 5,6-nido-C₂B₈H₁₂ with Mn(CO)₅Br. The structure of the complex [tmdaH][1,1,1-(CO)₃-isonido-1,2,4-MnC₂B₈H₁₀] was deter-mined by X-ray diffraction.