Ferrocene-containing tri- and tetranuclear cyclic copper(i) and silver(i) pyrazolates
- 作者: Titov A.1,2, Smol´yakov A.1,2, Rodionov A.1, Kosenko I.1, Guseva E.1, Zubavichus Y.3, Dorovatovskii P.3, Filippov O.1, Shubina E.1
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隶属关系:
- A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
- Peoples´ Friendship University of Russia
- National Research Center “Kurchatov Institute”
- 期: 卷 66, 编号 9 (2017)
- 页面: 1563-1568
- 栏目: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/241189
- DOI: https://doi.org/10.1007/s11172-017-1925-2
- ID: 241189
如何引用文章
详细
New tri- and tetranuclear macrocyclic silver(i) and copper(i) 3-ferrocenyl-5-(trifluoromethyl)pyrazolates were prepared: [{(3-((η5-C5H4)Fe(η5-C5H5))-5-(CF3)-Pz}M]3 (M = Cu (1), Ag (2)) and [{(3-(( η5-C5H4)Fe(η5-C5H5))-5-(CF3)-Pz}Cu]4 (3). The structures of compounds were established by X-ray diffraction analysis. In the crystalline state, a planar trinuclear silver-containing macrocycliс pyrazolate and a saddle-shaped tetranuclear copper-containing macrocycle are formed. The introduction of a bulky substituent, ferrocene, into the pyrazole ligand results in complete shielding of the acidic metal sites, which precludes the coordination of base molecules.
作者简介
A. Titov
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences; Peoples´ Friendship University of Russia
Email: shu@ineos.ac.ru
俄罗斯联邦, 28 ul. Vavilova, Moscow, 119991; 6 ul. Miklukho-Maklaya, Moscow, 117198
A. Smol´yakov
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences; Peoples´ Friendship University of Russia
Email: shu@ineos.ac.ru
俄罗斯联邦, 28 ul. Vavilova, Moscow, 119991; 6 ul. Miklukho-Maklaya, Moscow, 117198
A. Rodionov
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: shu@ineos.ac.ru
俄罗斯联邦, 28 ul. Vavilova, Moscow, 119991
I. Kosenko
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: shu@ineos.ac.ru
俄罗斯联邦, 28 ul. Vavilova, Moscow, 119991
E. Guseva
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: shu@ineos.ac.ru
俄罗斯联邦, 28 ul. Vavilova, Moscow, 119991
Ya. Zubavichus
National Research Center “Kurchatov Institute”
Email: shu@ineos.ac.ru
俄罗斯联邦, 1 pl. Akad. Kurchatova, Moscow, 123182
P. Dorovatovskii
National Research Center “Kurchatov Institute”
Email: shu@ineos.ac.ru
俄罗斯联邦, 1 pl. Akad. Kurchatova, Moscow, 123182
O. Filippov
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: shu@ineos.ac.ru
俄罗斯联邦, 28 ul. Vavilova, Moscow, 119991
E. Shubina
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: shu@ineos.ac.ru
俄罗斯联邦, 28 ul. Vavilova, Moscow, 119991