Synthesis of porphyrin-diazacrown ether and porphyrin-cryptand conjugates for fluorescence detection of copper(II) ions
- 作者: Averin A.1,2, Yakushev A.2, Maloshitskaya O.1, Surby S.3, Koifman O.3, Beletskaya I.1,2
-
隶属关系:
- Department of Chemistry, M. V. Lomonosov Moscow State University
- A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
- Ivanovo State University of Chemistry and Technology
- 期: 卷 66, 编号 8 (2017)
- 页面: 1456-1466
- 栏目: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/241101
- DOI: https://doi.org/10.1007/s11172-017-1908-3
- ID: 241101
如何引用文章
详细
Palladium-catalyzed amination was used for the synthesis of the macrocycles containing trioxadiamine linker and the fragments of either 3,3′-disubstituted biphenyl or 2,7-disubstituted naphthalene. Catalytic macrocyclization gives diazacrown ether-based cryptand with trioxadiamine linker. The synthesized compounds were involved in Pd-catalyzed arylation of zinc meso-(bromophenyl)porphyrin to obtain polymacrocyclic conjugates bearing one or two porphyrin units. The synthesized conjugates were studied as fluorescence sensing material and molecular probes for 18 metal ions. It was found that two of them are very promising fluorescent chemosensors for copper(II) cations.
作者简介
A. Averin
Department of Chemistry, M. V. Lomonosov Moscow State University; A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: averin@org.chem.msu.ru
俄罗斯联邦, 3 Build., 1 Leninskie Gory, Moscow, 119991; 4 Build., 31 Leninsky prosp., Moscow, 119991
A. Yakushev
A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: averin@org.chem.msu.ru
俄罗斯联邦, 4 Build., 31 Leninsky prosp., Moscow, 119991
O. Maloshitskaya
Department of Chemistry, M. V. Lomonosov Moscow State University
Email: averin@org.chem.msu.ru
俄罗斯联邦, 3 Build., 1 Leninskie Gory, Moscow, 119991
S. Surby
Ivanovo State University of Chemistry and Technology
Email: averin@org.chem.msu.ru
俄罗斯联邦, 7 Sheremetevskii prosp., Ivanovo, 153000
O. Koifman
Ivanovo State University of Chemistry and Technology
Email: averin@org.chem.msu.ru
俄罗斯联邦, 7 Sheremetevskii prosp., Ivanovo, 153000
I. Beletskaya
Department of Chemistry, M. V. Lomonosov Moscow State University; A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: averin@org.chem.msu.ru
俄罗斯联邦, 3 Build., 1 Leninskie Gory, Moscow, 119991; 4 Build., 31 Leninsky prosp., Moscow, 119991