Modern level for properties prediction of iodine-containing organic compounds: the halogen bonds formed by iodine
- 作者: Bartashevich E.1, Grigoreva E.1, Yushina I.1, Bulatova L.1, Tsirelson V.2
-
隶属关系:
- South Ural State University
- D. I. Mendeleev University of Chemical Technology
- 期: 卷 66, 编号 8 (2017)
- 页面: 1345-1356
- 栏目: Reviews
- URL: https://journals.rcsi.science/1066-5285/article/view/241052
- DOI: https://doi.org/10.1007/s11172-017-1898-1
- ID: 241052
如何引用文章
详细
The modern concepts on specific features of anisotropy of the electron density of valence shells of bound atoms and chemical bonds providing the successful description of the properties of halogen bonds formed by the iodine molecule in compounds with useful physicochemical properties are generalized in the review. The prognoses of basicity by the diiodine basicity scale for the nitrogen-containing compounds are illustrated. The regularities and peculiarities of shifting bands in Raman spectra of iodine-containing organic crystals are considered. The methodical and specific problems of modeling appeared when the electronic characteristics of the iodine compounds are estimated and briefly discussed.
作者简介
E. Bartashevich
South Ural State University
编辑信件的主要联系方式.
Email: bartashevichev@susu.ru
俄罗斯联邦, 76 prosp. Lenina, Chelyabinsk, 454080
E. Grigoreva
South Ural State University
Email: bartashevichev@susu.ru
俄罗斯联邦, 76 prosp. Lenina, Chelyabinsk, 454080
I. Yushina
South Ural State University
Email: bartashevichev@susu.ru
俄罗斯联邦, 76 prosp. Lenina, Chelyabinsk, 454080
L. Bulatova
South Ural State University
Email: bartashevichev@susu.ru
俄罗斯联邦, 76 prosp. Lenina, Chelyabinsk, 454080
V. Tsirelson
D. I. Mendeleev University of Chemical Technology
Email: bartashevichev@susu.ru
俄罗斯联邦, 9 Miusskaya pl., Moscow, 125047