Conditions of catalytic hydrogenolysis for the simultaneous reduction of azido group and debenzylation of chitooligosaccharides. Synthesis of biotinylated derivatives of chitooligosaccharides
- 作者: Yudina O.1, Tsvetkov Y.1, Nifantiev N.1
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隶属关系:
- N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
- 期: 卷 65, 编号 12 (2016)
- 页面: 2937-2942
- 栏目: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/239668
- DOI: https://doi.org/10.1007/s11172-016-1681-8
- ID: 239668
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详细
Hydrogenation over Pd(OH)2/C in a methanol—water—acetic acid mixture allows one to carry out the efficient simultaneous reduction of the azido group and remove the benzyl groups in 2-azidoethyl glycosides of benzylated chitooligosaccharides. The obtained 2-aminoethyl glycosides of free chitooligosaccharides were converted to the corresponding biotinylated conjugates serving as tools for glycobiological investigations.
作者简介
O. Yudina
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: nen@ioc.ac.ru
俄罗斯联邦, 47 Leninsky prosp., Moscow, 119991
Yu. Tsvetkov
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: nen@ioc.ac.ru
俄罗斯联邦, 47 Leninsky prosp., Moscow, 119991
N. Nifantiev
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: nen@ioc.ac.ru
俄罗斯联邦, 47 Leninsky prosp., Moscow, 119991