Complexation of heterocyclic azo compounds with transition metal ions as found by the laser-induced desorption/ionization method
- 作者: Grechnikov A.1, Borodkov A.1, Simakina Y.1, Arabova Z.1, Mikhailova A.1, Kuz’min I.1, Dedkov Y.1, Minin V.2
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隶属关系:
- V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences
- N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- 期: 卷 65, 编号 12 (2016)
- 页面: 2789-2794
- 栏目: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/239500
- DOI: https://doi.org/10.1007/s11172-016-1657-8
- ID: 239500
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详细
The Pd, Mn, La, and Rh complexes with the heterocyclic azo compounds were studied by the laser-induced electron transfer desorption/ionization (LETDI) method. The optimum parameters of laser irradiation were found, and the compositions of the complexes were determined. The quantum chemical simulation of the compositions of the complexes was performed on the basis of the data of mass spectrometry. It is shown that laser-induced electron transfer desorption/ionization is an effective tool for the high-sensitive determination and identification of metal complexes.
作者简介
A. Grechnikov
V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: grechnikov@geokhi.ru
俄罗斯联邦, 19 ul. Kosygina, Moscow, 119991
A. Borodkov
V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences
Email: grechnikov@geokhi.ru
俄罗斯联邦, 19 ul. Kosygina, Moscow, 119991
Ya. Simakina
V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences
Email: grechnikov@geokhi.ru
俄罗斯联邦, 19 ul. Kosygina, Moscow, 119991
Z. Arabova
V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences
Email: grechnikov@geokhi.ru
俄罗斯联邦, 19 ul. Kosygina, Moscow, 119991
A. Mikhailova
V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences
Email: grechnikov@geokhi.ru
俄罗斯联邦, 19 ul. Kosygina, Moscow, 119991
I. Kuz’min
V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences
Email: grechnikov@geokhi.ru
俄罗斯联邦, 19 ul. Kosygina, Moscow, 119991
Yu. Dedkov
V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences
Email: grechnikov@geokhi.ru
俄罗斯联邦, 19 ul. Kosygina, Moscow, 119991
V. Minin
N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: grechnikov@geokhi.ru
俄罗斯联邦, 31 Leninsky prosp., Moscow, 119991